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Once Br2 is formed, the reaction proceeds much like other free-radical halogenation reactions: homolytic cleavage of the Br2 with light or head (initiation), followed by abstraction of the allylic H (propagation step #1) and subsequent reaction of this radical with another equivalent of Br2 to give the desired product. The remaining Br radical then reacts with another equivalent of the hydrocarbon in this chain reaction until the limiting reagent is consumed.
The M.S. degree programs in Biochemistry and in Biophysics are useful for students who prefer to undertake research training without the longer-term commitment required for the Ph.D. degree. It is also useful for students interested more in the technical aspects of research rather than in careers as research directors. The program requires about 3 years on average to complete and the successful defense of an independent research dissertation is required. About half the time required to earn the degree is spent on advanced coursework and professional seminars, and the other half is devoted to research undertaken in the laboratory under the close supervision of a faculty mentor. Financial support is available. To apply, applicants first submit the free BBMB online application found on the department website, which is used as a screening tool.
The Ph.D. programs in Biochemistry and in Biophysics are designed to train students in the ability to independently conceive and carry out original research in the general area of the chemistry or physics of the processes of life. The programs require about 5-6 years on average to complete and the successful defense of an independent research dissertation. The majority of the time required to earn the degree is spent doing research on the dissertation project in the laboratory under the close supervision of a faculty mentor. Considerable time also is devoted to advanced coursework and professional seminars. Financial support is available. To apply, applicants first submit the free BBMB online application found on the department website, which is used as a screening tool. Students may enter the Biochemistry or Biophysics Ph.D. degree programs either as a rotation student in the fall semester or as a direct admit to a faculty research group at any time during the year.
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